The making of best quality anode in Inalum - Part 1: Paste Plan — Transcript
Full transcript
- 0:02[Music]
- 0:28[Music]
- 0:34hello it is a pleasure to be able to
- 0:36meet with my comrades in aluminium
- 0:38smelter World in this occasion I want to
- 0:42present the making of anod carbon in our
- 0:44company hope it can give inspiration to
- 0:47younger employees especially for those
- 0:49who work in Platinum in alen any ideas
- 0:52for the betterness of this presentation
- 0:54material is waited thank you
- 0:57[Music]
- 1:13carbon roll in aluminium
- 1:15smelter one the hall here ruled
- 1:18process aluminum oxide all 203 is
- 1:22dissolved in Molen cry alina3
- 1:25L6 it is decomposed electrolytically
- 1:27between carbon and aluminum electrodes
- 1:29at about 950° C to aluminum and
- 1:33oxygen the carbon anod is continuously
- 1:36consumed by reacting with the oxygen to
- 1:38give carbon dioxide
- 1:40CO2 to all 23 + 3 C equals for all + 3
- 1:45CO2 two reasons why carbon is used as
- 1:50electric carbon are highly stable
- 1:52requiring high temperature to react even
- 1:54with
- 1:55oxygen carbon has the highest melting
- 1:58and sublimation point of all elements
- 2:01thus irrespective of its allotropic form
- 2:04carbon remains solid at higher
- 2:06temperatures than the highest melting
- 2:09point Metals such as tungsten
- 2:11perenium although thermodynamically
- 2:14prone to oxidation carbon resists
- 2:16oxidation more effectively than elements
- 2:19such as iron and copper that are weaker
- 2:22reducing agents at room
- 2:24temperature three carbon known in
- 2:26various multi-atomic structures with
- 2:28different molecular config ation called
- 2:31allotropes the three relatively
- 2:33well-known allotropes of carbon are
- 2:35morphis carbon graphite and Diamond
- 2:38which one of these allotropes can be
- 2:41used as anal in aluminium reduction
- 2:47process
- 2:49amorphous the amorphous form is
- 2:51essentially graphite but not held in a
- 2:53crystalline macro
- 2:56structure
- 2:57graphite at normal pressur carbon takes
- 3:00a form of graphite in which each atom is
- 3:03bonded
- 3:04trigonally two three others in a plane
- 3:06compos the fused hexagonal Rings the
- 3:10resulting network is two
- 3:11dimensional and the resulting flat
- 3:13sheets are stacked and loely bonded
- 3:15through weak van vse forces this gives
- 3:20graphite its softness and its cleaning
- 3:22properties the sheets slip easily past
- 3:24one another because of the
- 3:26delocalization of one of the outer
- 3:28electrons of each atom to form a fight
- 3:31Cloud graad fight conducts electricity
- 3:34but only in the plane of each calent
- 3:36bonded
- 3:38sheet
- 3:40Diamond that very high pressured carbon
- 3:43forms the more compact Petro Diamond
- 3:46here each atom is
- 3:48bonded tetrahedrally to four others thus
- 3:51making a three-dimensional network of
- 3:53puckered six membered rings of
- 3:55atoms that's why Diamond to be an
- 3:57excellent electrical insulator
- 4:03so it is obviously that alrod which is
- 4:05able to be used as anod material is
- 4:12graphite this is micro structure of
- 4:15graphite made asod due to the highest
- 4:18temperature might be possible happen in
- 4:20aluminium reduction pot still below 1,
- 4:24100° C so it is no need to prepare
- 4:27denser graphite just enough in between
- 4:301,000° c 1, 1400° c
- 4:35[Music]
- 5:07what criteria are needed from
- 5:09[Music]
- 5:11anod criteria for anodes one high
- 5:16resistance to gasification in order to
- 5:18minimize dusting and excess of carbon
- 5:20consumption two sufficient mechanical
- 5:23strength for structural integrity and
- 5:25handling three Clow specific electrical
- 5:28resistance value for power consumption
- 5:31four high Elemental Purity to avoid
- 5:34contaminating the reduced metal and
- 5:36excess anal consumption five high
- 5:39thermal shock resistance to avoid cell
- 5:45disruptions where is our positioned in
- 5:47these tough
- 5:50demand one
- 5:53gd80 typical
- 5:561.55
- 5:581.65 in Alum 1.64
- 6:031.69 status better two
- 6:08bd80 typical
- 6:111.50
- 6:131.60 in Alam
- 6:161.59
- 6:181.65 status better three AP typical 0.5
- 6:272.0 in Alam
- 6:300.3
- 6:320.5 status better for CS typical 40 55
- 6:41in Alum 28 49 status better five FS
- 6:50typical 8.0
- 6:5314.0 in Alam 11.0
- 6:5815.0 status better 6 TC typical 3.0
- 7:074.5 in Alum 3.2
- 7:114.0 status 7
- 7:16R2 typical 65 990 in Alum 89
- 7:2393 status better 8 r rc2
- 7:30typical 84
- 7:3295 in Alum 95
- 7:3797 status
- 7:47better great is it so difficult to
- 7:50achieve these
- 7:56figures unfortunately no at all
- 8:00no sacred matters
- 8:05here everything has been striped by R&D
- 8:14carbon we just follow it in the correct
- 8:16direction and
- 8:23doing some proper adjustments to adapt
- 8:26plant condition and current
- 8:31raw material is being used here the
- 8:34steps of anod
- 8:44manufacturer let's talk about the first
- 8:47step raw
- 8:50material
- 8:57CX caline Coke
- 9:00green Coke is residual fraction of
- 9:02petroleum or crude oil which has a very
- 9:04weak amorphous structure and still has
- 9:06volatile matter in between 8 up to 12%
- 9:09cook through delayed cooking process
- 9:11then calcinated by giving heat treatment
- 9:13to make it as electric quality Coke or
- 9:15caline
- 9:19Coke the Coke's texture
- 9:43smelter grade Cokes should have not too
- 9:45high real density and having tolerable
- 9:47impurities content to High real density
- 9:50will bring worse consequence during
- 9:52production and at last giving impact to
- 9:56Quality pitch
- 10:01for bonding grains it is used binder
- 10:04from liquefied
- 10:08CDP colar pitch col tar which is dewied
- 10:13heated up to approximately 350° Kel use
- 10:16and finally flash cold distillation
- 10:18process will become cold tar pit so what
- 10:22is cold tar pit complex mixture between
- 10:25polycyclic aromatic and heterocyclic
- 10:27compounds with aliphatic and function
- 10:29groups attached to the rinks
- 10:31approximately 90% of col tar pitch
- 10:34consists of three up to seven ring
- 10:35aromatic compounds with molecular
- 10:37weights ranging between 170 up to 380
- 10:41the remaining portion is made up of
- 10:43higher molecular weight carbonaceous
- 10:45materials that are not soluble why col
- 10:48tar pitch is choosed as binder one
- 10:51strong adherence or bonding to the
- 10:53aggregate two satisfactory wedding
- 10:57characteristics three High cooking value
- 11:00yielding a strong structure fourth low
- 11:03relative cost and ready avability in
- 11:05large quantities five low Ash and sulfur
- 11:09content six smooth volatile emission
- 11:12across the anode Bay temperature
- 11:22range cold tar pitch properties one
- 11:26softening point is used to describe the
- 11:28change in Pitch between a solid to
- 11:30liquid form two cooking value is an
- 11:34indicator of the likely residual carbon
- 11:35retained in the form of pitch Coke after
- 11:38baking three pitch density and CH ratio
- 11:42is an indication of the pitch
- 11:43aromaticity denser pitches have a higher
- 11:46aromaticity and thus produce denser
- 11:48baked anodes kesy of a binder carbon
- 11:50yield four quinine insoluble or Qi
- 11:54describes the amount of particles in
- 11:55soluble in quinine solvent alpha
- 11:57particles to be qi
- 11:59there are two type of Qi one primary
- 12:03formed in the coke oven so it is good
- 12:05for anode quality to secondary and
- 12:08mesophase formed by additional heat
- 12:09treatment note mesophase is harmful to
- 12:12anode quality five toine and solubles or
- 12:16TI beta resin is TI reduced by Qi it
- 12:20will give beneficial to bond your
- 12:22forming ability of pitch with Coke
- 12:24particles six viscosity is used to guide
- 12:28handling pitch liquid form and paste
- 12:29mixing and forming seven distillation of
- 12:33lighter fractions lower temperature
- 12:35distillation of the lighter fractions is
- 12:37a measure of the pitch volatile content
- 12:39and lighter fractions that are released
- 12:41in the temperature range 270° cus up to
- 12:45360°
- 12:46CSUS 8 ash content is an indicator of
- 12:50total impurities in
- 12:56Pitch the most important parameter from
- 12:59CDP is s
- 13:17p the material comes from rotting plant
- 13:21according to R&D carbon dust and Grains
- 13:24less than 1 mm must not be recycled and
- 13:26treated as waste
- 13:36how it could be what is the reason for
- 13:39R&D carbon the answer will come in a
- 13:46moment the last sodium content increases
- 13:49higher in line with thiner grains so
- 13:53that's why it is strictly not
- 13:54recommended in order to get better anal
- 13:57the bad character H can tent in ther
- 13:59should be minimized in usage for
- 14:03recycling that's all for the first step
- 14:06of anod manufacture next I'm going to
- 14:09explain how to make
- 14:20paste let's talking about the second
- 14:23step making good
- 14:26paste paste
- 14:31raw materials for paste are Aggregate
- 14:33and binder let's talk these raw
- 14:35materials one by one starting with
- 14:38aggregate aggregate is a mixing of Cokes
- 14:40and butts there are two preconditions
- 14:43should be fulfilled to get better
- 14:45aggregate one aggregate grains
- 14:47composition should be in the determined
- 14:53grometry according to rmd carbon there
- 14:56are four possibilities of grometry
- 14:59one intended to make denser green block
- 15:02with low porosity which is at last after
- 15:04baking it is H we can get high r value
- 15:07this kind of granulometry is our choice
- 15:10two intended to make denser green block
- 15:13with low porosity which is at last after
- 15:15baking it is hoped we can get low AP
- 15:17value unfortunately this kind of
- 15:20granulometry caused weaker physical
- 15:22strength three intended to make stronger
- 15:25anal after baking but unfortunately this
- 15:27kind of granulometry has lower R and A
- 15:30values fourth it must be avoided the
- 15:33worst grometry
- 15:38option our choice granulometry no one in
- 15:41implementation organized such
- 15:46as the granulometry or distribution of
- 15:49grain
- 15:50size to have denser anod the
- 15:54grometry should be arranged as the first
- 15:57course 16 mm down to 8 mm is
- 16:0110% the second course 8 mm down to 4 mm
- 16:05is
- 16:0610% medium to millime down to
- 16:090.125 mm is
- 16:1230% find below 0.125 mm is 50%
- 16:37two aggregate impurities side. e sodium
- 16:40calcium nickel and padium should be
- 16:42lower than determined values impurities
- 16:46should be attained in certain tolerable
- 16:51range catalytic
- 16:53impurities impurities which give bad
- 16:55impact to metal quality silicium Iron
- 16:58vadium nickel titanium and Lead
- 17:01impurities which give bad impact to
- 17:03anode consumption vadium nickel sodium
- 17:06potassium and calcium impurities which
- 17:09give bad impact to energy and current
- 17:11efficiency padium and
- 17:13phosphorus impurities which give bad
- 17:16impact to pollution sulfur hydrogen and
- 17:22Lead now I show how to prepare Cokes
- 17:33Co dis harded from silos by ratio high
- 17:35sulfur low sulfur equals 60 minutes and
- 17:3840
- 17:50seconds through damper DP if Coke Silo
- 17:53level is still above 40% no need bypass
- 18:09in server sr1 grains separated into the
- 18:12size batch above 18 mm and in range
- 18:16three 18 mm
- 18:30in silver sr2 grains separated into
- 18:33three size batch range three 1 mm range
- 18:371 0.2 mm and Below 0.2
- 18:53mm grains with size over 18 mm is
- 18:56crushed by Crusher to be ther than 5 mm
- 19:00and then send back to
- 19:13sr1 the Surplus in in one feedback into
- 19:16Crusher to increase finer grain size
- 19:19product
- 19:32to get finess grains with size below 0.2
- 19:35mm M into
- 19:48milk the Surplus inin to feedback to
- 19:51tube M to increase production of finess
- 20:07fine comes from dust collecting system
- 20:09or bag filters
- 20:35pay attention on the texture comparison
- 20:37between coses and butts
- 21:00let's magnify and after doing it can you
- 21:02catch any differences between them
- 21:31black color on coke is more dominant
- 21:33than butts these black color spots are
- 21:36assumed as
- 21:38porosity butts have denser texture than
- 21:41Cokes or in other words butts is weer
- 21:44than CES next images show which one is
- 21:47the best composition we should take
- 21:50composition one one all is buts two at
- 21:56the same volume it is weer than
- 21:58composition two and three three bonding
- 22:01among grains is not enough strong due to
- 22:03have only gluing and no
- 22:05anchoring for their reactivity and a
- 22:08permeability of the product anod will be
- 22:11worse so obviously that composition one
- 22:14is not
- 22:22recommended composition two one all is
- 22:26CX two at the same volume it is lighter
- 22:30than composition one and three three it
- 22:33is going to consume more binder four
- 22:37many problems will occur after
- 22:39baking so obviously that composition to
- 22:42is not also
- 22:49recommended composition three one mix
- 22:53between butts and cokes two at the same
- 22:57volume it has an ideal weight three
- 23:00optimal pitching can get obviously this
- 23:04is the composition should be applied
- 23:31point to be aimed is how to get the best
- 23:33composition between butts C in aggregate
- 24:17Based on data showing in the chart there
- 24:19are three conditions should be paid
- 24:21attention carefully one benefit got by
- 24:24using corer butts grain grain size in
- 24:27between 0 5 til to 16 mm is reducing
- 24:30porosity up to
- 24:3270% two meanwhile corser Co grain
- 24:36decreases 50% porosity three significant
- 24:40impact coming from finer grain either
- 24:42CES or butts let's say it's able to
- 24:45reduce porosity above
- 24:4790% in this range area it's better to
- 24:50utilize butts in order to increase
- 24:53weight and at last will be increased the
- 24:55density
- 25:10in this range area it's better to
- 25:12utilize butts in order to increase
- 25:14weight and at last will be increased the
- 25:16density
- 25:28in this range area consider to use same
- 25:30portion of Cokes and
- 25:42butts maximize Cokes in this area there
- 25:46are no significant white difference this
- 25:48can also avoid dirty butts thus entering
- 25:51the aggregate so let's skin the density
- 25:54of butts and cokes on each areas
- 26:06from the granulometry composition we
- 26:08have chosen we can get
- 26:20data now we make a simulation to look
- 26:22for the best composition to get higher
- 26:24density
- 26:49let's do trial and error method to fill
- 26:51the table
- 27:24but ratio equals 34% and vbd aggregate
- 27:27equals 0
- 27:299,323 g/
- 27:31CC CDP must be in liquid form in order
- 27:34to act as binder but before talking
- 27:36further please acknowledge information
- 27:39regarding
- 27:45CDP in depth with CDP one by using many
- 27:50different kind of solvent like alcohol
- 27:53toine and
- 27:54quinoline substances on Pitch can be
- 27:57grouped as alzin molecular weight is
- 28:00under 100 toine soluble molecular weight
- 28:04100 tilted
- 28:061,000 quinoline soluble molecular weight
- 28:091,000 till to
- 28:183,000 two the sticky characteristic of
- 28:22pitch conted mainly by Beta resin which
- 28:25is a difference of quinoline insoluble
- 28:27toine ins soluble beta resin equals KY T
- 28:32note more beta resin greater than better
- 28:34sticky characteristic of
- 28:36binder so to represent more beta Risin
- 28:39greater than increase amount of key this
- 28:42is commonly done by add lighter
- 28:44fractions into
- 28:46desolation this will increase the risk
- 28:48of metaphase appearance
- 29:07three sometimes too high key content
- 29:09will give bad impact to pump
- 29:12performance it's strainer clog by a thin
- 29:14layer so be wise in choosing CDP
- 29:29mesophase theoretical
- 29:31review when Pitch is made aeromatic
- 29:34systems are growing up in thermolyses
- 29:36and leads to a
- 29:37sufficiency High concentration of large
- 29:40aeromatic systems with molecular weights
- 29:42approximate to 600
- 29:44a.m mesophase occurs if some critical
- 29:47parameters EG viscosity heating rate and
- 29:50others are met the mesophase is strongly
- 29:53an isotropic and takes a spherical form
- 29:55in order to minimize its surface energy
- 30:03further about
- 30:04mapase at further heating or increasing
- 30:07residance time more and more mesophase
- 30:09is formed from the isotropic pitch the
- 30:12size of the mesophase Spheres increases
- 30:14and they start to coales into bigger and
- 30:17bigger anisotropic
- 30:19areas the transition from a flowing or
- 30:21plastic pitch to a rigid SM Coke green
- 30:23Coke occurs in a narrow temperature
- 30:26interval around 500 ° C still the
- 30:29significant amount of hydrogen is
- 30:31present but most will be gone when the
- 30:33temperature reaches 800° C so obviously
- 30:38that too much mesap phase with high
- 30:40diameter will leave behind voids after
- 30:42baking process it's clearly harming anod
- 30:45quality and this is so
- 30:51bad this data informed the amount of
- 30:53mesophase and heat adjustment to keep
- 30:56hitch viscosity in order to keep as good
- 30:58binder
- 31:02agents this data informed the additional
- 31:04percentage of pitch in order to cover
- 31:06the existence of mesophase in
- 31:24binder what kind of pitching shall it be
- 31:26achieved in order to get good hod let's
- 31:29no kind of level pitch given into paste
- 31:32case
- 31:35one under
- 31:40pitching under pitching symptoms one dry
- 31:44paste two cracks on GB three underling
- 31:50lack of volatiles fourth poor mechanical
- 31:54properties five air burn problem in pot
- 31:58case
- 32:01two over
- 32:07pitching watch out over pitching at last
- 32:11and bond grains due to co greater than
- 32:13adhesion over ping
- 32:16symtoms one wet paste two glowing paste
- 32:22three extreme shrinkage four stum hole
- 32:26deformation SL slide ping five crack
- 32:30during baking excessive de
- 32:32validation six sticking of packing
- 32:36material seven high air permeability
- 32:39compressive strength and Young's
- 32:43modulus so what does the optimal
- 32:46pitching look like case
- 32:51three optimal
- 32:55pitching optimal pitching one still left
- 33:00void two no separate bonding among
- 33:03grains now we have came to how to
- 33:06achieve optimal hit thinging by setting
- 33:08correct binder
- 33:10ratio to do this firstly we have to know
- 33:14the limit of over pitching by comparing
- 33:16slumping on BB
- 33:38watch out look at figures 15% and next
- 33:42higher level in this range gb80 is not
- 33:46in line with bb80 anymore what does it
- 33:50mean yes of course gb8 can be made
- 33:54Higher by increasing binder level but
- 33:57result after baking delimitate it so
- 34:01this phenomenon becoming the first sign
- 34:05of over
- 34:07pitching secondly check the sticking
- 34:09either amount or pattern on
- 34:13BB remember there are two kind of sticky
- 34:17things on BB just after discharging from
- 34:20baking furnace one isolation CX two
- 34:26another blocks
- 34:28whatever the sticking kind this pointing
- 34:31to the second indicator of over pitching
- 34:34note we apply constrainted value
- 34:372% of sticking on BB from the total BB
- 34:44discharged listing the figures into Data
- 34:46Bonk for the next product please keeping
- 34:49this data Bonk
- 34:51update are there any different
- 34:53methods there are two methods to detect
- 34:56binder sufficiency
- 34:58it should be done by operator during
- 35:00inspection one physical inspection on GB
- 35:04condition looking for symptoms of over
- 35:07pitching like glowing on GB crust length
- 35:11shrinkage greater than 3
- 35:13mm two observation on paste condition
- 35:17just before forming like flexity tough
- 35:21for fragile now we have come into the
- 35:24making of
- 35:26paste
- 35:56e e
- 36:31beware kept the temperature of this
- 36:33pasted product all plus 10° see than
- 36:36temperature needed in forming machine
- 36:38what should be paid attention in
- 36:40knitting or mixing
- 36:43operation what should be paid attention
- 36:45inting or mixing
- 36:47operation one softening point is P value
- 36:50of the current
- 36:53CDT important an Alum using balling
- 36:57methods
- 36:58so it has to be adjusted by -5° C for
- 37:02operation purpose correlation between
- 37:06softening point and mixing temperature
- 37:08is described by equation Y = 1.48 X +
- 37:145.6 where y equals mixing temperature x
- 37:18equals softening point for
- 37:20example if SB equals 113° c so mixing
- 37:25temperature equals 172 8°
- 37:29C by implementing Black's principle we
- 37:32have formula for thermal
- 37:36balance let's say we have data s p of
- 37:40CDP from India equals 113° c binder
- 37:44ratio equals
- 37:4714.5% heating up temperature for CDP
- 37:50equals 210 de C heating up temperature
- 37:54for aggregate equals 160° c
- 37:57how big additional temperature should be
- 38:00given answer first we are looking for
- 38:03mixing
- 38:04temperature put in SB value into the
- 38:07first Formula we have
- 38:09172.2 4° C put in data into the second
- 38:13formula we have equation
- 38:160.145 asterisk 210 T =
- 38:200.855 asterisk T 160 so we will get t
- 38:26equal 16 7.25 de C greater than we need
- 38:305.59 de C more let's try to implement
- 38:34this
- 38:37formula please follow the movement of
- 38:39star pointer on the
- 38:55chart this situation takes place if no
- 38:58additional heat so it is strictly
- 39:07prohibited in order to achieve
- 39:09appropriate mixing
- 39:11temperature an additional heat from
- 39:13meter should be
- 39:24given two the second important fact
- 39:27during kneading process is specific
- 39:29mixing
- 39:31energy mixing energy the best practice
- 39:35in in Alam to get homogeneous taste is
- 39:38by
- 39:39implementing mixing energy inside a
- 39:41tight space from 8.9 up to 9.1 kilow
- 39:46flash T paste below this range paste
- 39:49looks dry Above This range paste looks
- 39:54wet three mixing time
- 40:09look either shorten or prolong the
- 40:11mixing time in fact it is no
- 40:18use important stuff related to mixing
- 40:21time too short makes under pitching too
- 40:24long may destroy granulometry of the
- 40:26grains
- 40:28what we want is sufficient time in order
- 40:30to give binder and finess centering
- 40:34macroporosity of grains to create anchor
- 40:36bonding among binder Matrix outside and
- 40:40inside
- 40:41grains note it is applied mixing time
- 40:44around 5 minutes please look at
- 40:47description comes in a moment inside
- 40:50meter forces C binder Matrix to enter
- 40:53Cox grains
- 41:00after cooling this binder Matrix will
- 41:02build stronger bonding compared to
- 41:03gluing only
- 41:30let's talk about the two Road step paste
- 41:36forming steps of shaking machine
- 41:41operation One charging paste into the
- 41:44ready mold note paste is not something
- 41:49liquid so it cannot fulfill the whole
- 41:52Space inside the mold automatically we
- 41:55have to arrange hits spreading evenly
- 41:58during filling time in order to avoid
- 42:01sticking of paste in the mold wall
- 42:04precaution actions should be done before
- 42:06forming like a heating up or keeping
- 42:09temperature stable B spraying special
- 42:12oil and water in the wall
- 42:14regularly see removing resident the mold
- 42:17from the previous
- 42:24forming in order to get one side having
- 42:27better density we can increase thickness
- 42:30on this side paste profile intentionally
- 42:33created not
- 42:35flat or you can't try for the opposite
- 42:39side two put cover weight down and then
- 42:43lock up what should be paid attention
- 42:46regarding cover weight a to waight the
- 42:49cover weight leads to grain
- 42:50destruction and thus to an insufficient
- 42:53strength of the EG node B to light the
- 42:56cover weight result in a poor density
- 42:59and an excessive gas
- 43:03permeability note specific forming
- 43:06pressure versus anal
- 43:08crosssection vation y = -
- 43:124591 x superscript 3 + 1655 x
- 43:16superscript 2 1931 x +
- 43:208.7 y equals specific forming pressure
- 43:23bar x equal anod crosssection m
- 43:26superscript 2
- 43:28two three evacuating unnecessary gas
- 43:32repa emission by vacuum usually for
- 43:35better result man make it below 120
- 43:42MPR it's time for vibrating now
- 44:05fourth vibro compassion operation
- 44:08tips paste temperature put into the mold
- 44:11should be in between
- 44:12155° C til to 165° C avoid paast
- 44:18temperature variance Federal into mold
- 44:19vary more than plus SL 2° C in order to
- 44:24get better result it is strongly
- 44:26suggested to make put paste temperature
- 44:29close to the highest constraint equals
- 44:32165° c this effort is going to decrease
- 44:36viscosity so it is easier for grains
- 44:39moving to find its Optimum place in mold
- 44:42during
- 44:49vibration DB and are o this is control
- 44:54program on the vro comping machine
- 44:57control principle by this program can be
- 44:59explained one the first priority the
- 45:03machine look for gb80 value or GB height
- 45:07if one of these Target is found then
- 45:10stop two secondly if during set maximum
- 45:14fpr compassion running these two Targets
- 45:17don't get then
- 45:18stop note the machine is completed by
- 45:21weighing scale and height sensor so it
- 45:25is able to adjust the amount of
- 45:27paste Federal if the height of previous
- 45:29block down
- 45:36below
- 45:38beware just after forming block exhibit
- 45:41a low mechanical stability due to the
- 45:43softness of binder pitch in order not to
- 45:47damage the block handling with care is a
- 45:50must so to release block from mold
- 45:53Pusher should be run gently it finish
- 45:57prepare to form next block
- 46:29cooling after forming after forming GB
- 46:32temperature is still high it exhibits
- 46:35low mechanical stability due to this
- 46:38reason it needs to be
- 46:40cooled this is very important phase on
- 46:42the making of anodes mishandling will
- 46:45cause damage on GB one cool to intensify
- 46:49may
- 46:50cause surface fissures are generated due
- 46:53to shrinkage of GB crust two
- 46:56insufficient cooling may
- 46:58cause damage on GB during subsequent
- 47:01handling storage and
- 47:03processing here in a moment show to you
- 47:06the steps of cooling
- 47:16phase be careful this period needs a lot
- 47:19of care or just leave it more safe
- 47:32this is a sample when weak crust is in
- 47:34dangerous period but handled
- 48:06just before I end this
- 48:08presentation let me explain how to keep
- 48:11the
- 48:23quality first of all you should know
- 48:26well the basic te knowledge NGB
- 48:28production do you know
- 48:37it the most important thing from paste
- 48:40plant to make sure the GB product always
- 48:43in the good quality or just to control
- 48:46impurities content coming from raw
- 48:48material and get ideal
- 48:50gb80 as simple as that isn't it
- 48:58I have developed the formula to predict
- 48:59ano quality based on GD data calculation
- 49:03result with this Formula compared by
- 49:05actual result show just the little
- 49:08difference plus minus
- 49:141% 1 R2 equal -
- 49:18216218 then I
- 49:2197215 3 v 105.4 one5 no plus 190 . 783
- 49:27CA + 1.6 for 2 s 2.33 6 gb8 + 106.1
- 49:34183 where R2 equals air reactivity
- 49:37residue percent then I equals nickel
- 49:39content percent V equals padium content
- 49:42percent a equals sodium content percent
- 49:45C equals calcium content percent s
- 49:48equals sulfur content
- 49:53percent two r r c o 2 = -
- 49:58238.9 for1 c 24.25 3 46.0 to2 V plus
- 50:051.15 s + 9652
- 50:084 where R rc2 equals Co to reactivity
- 50:13residue percent C equals calcium content
- 50:15percent equals sodium content percent V
- 50:19equals padium content percent s equals
- 50:21sulfur content percent
- 50:28so by controlling each impurities
- 50:30involved and arrange ideal gb80 best
- 50:32quality anodes are in our
- 50:35hand regarding achievement and ideal gb8
- 50:38like or dislike it depends on the
- 50:40goodness of equipment and skill and
- 50:43blending raw material experience is the
- 50:46key but here I just share some tricks
- 51:03there are two conditions Down Under and
- 51:05Over the Top basically both of them are
- 51:09caused by
- 51:10grometry counter measure for down under
- 51:13one increase the usage of corser butts
- 51:16material if enabled two in case you
- 51:20don't have corser butts consider
- 51:22increased butts
- 51:23ratio three in case you have only
- 51:26sufficient butt stock consider to
- 51:28decrease production capacity counter
- 51:31measure for over the top one decrease
- 51:35the usage of corser butts material if
- 51:37enabled two in case you don't have finer
- 51:41butts consider to crush it three in case
- 51:45you have too much butt stock consider to
- 51:47increase production
- 51:54capacity in this position the cause is
- 51:57still same with down
- 51:59undercase just use the same trick to
- 52:01overcome this
- 52:08problem in this position the cause is
- 52:11informing machine or Neer just follow
- 52:14the tricks already explained to overcome
- 52:16this
- 52:25problem for
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