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The making of best quality anode in Inalum - Part 1: Paste Plan — Transcript

by Edwin EA · 4,252 words · 755 segments · language en · Watch on YouTube

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  1. 0:02[Music]
  2. 0:28[Music]
  3. 0:34hello it is a pleasure to be able to
  4. 0:36meet with my comrades in aluminium
  5. 0:38smelter World in this occasion I want to
  6. 0:42present the making of anod carbon in our
  7. 0:44company hope it can give inspiration to
  8. 0:47younger employees especially for those
  9. 0:49who work in Platinum in alen any ideas
  10. 0:52for the betterness of this presentation
  11. 0:54material is waited thank you
  12. 0:57[Music]
  13. 1:13carbon roll in aluminium
  14. 1:15smelter one the hall here ruled
  15. 1:18process aluminum oxide all 203 is
  16. 1:22dissolved in Molen cry alina3
  17. 1:25L6 it is decomposed electrolytically
  18. 1:27between carbon and aluminum electrodes
  19. 1:29at about 950° C to aluminum and
  20. 1:33oxygen the carbon anod is continuously
  21. 1:36consumed by reacting with the oxygen to
  22. 1:38give carbon dioxide
  23. 1:40CO2 to all 23 + 3 C equals for all + 3
  24. 1:45CO2 two reasons why carbon is used as
  25. 1:50electric carbon are highly stable
  26. 1:52requiring high temperature to react even
  27. 1:54with
  28. 1:55oxygen carbon has the highest melting
  29. 1:58and sublimation point of all elements
  30. 2:01thus irrespective of its allotropic form
  31. 2:04carbon remains solid at higher
  32. 2:06temperatures than the highest melting
  33. 2:09point Metals such as tungsten
  34. 2:11perenium although thermodynamically
  35. 2:14prone to oxidation carbon resists
  36. 2:16oxidation more effectively than elements
  37. 2:19such as iron and copper that are weaker
  38. 2:22reducing agents at room
  39. 2:24temperature three carbon known in
  40. 2:26various multi-atomic structures with
  41. 2:28different molecular config ation called
  42. 2:31allotropes the three relatively
  43. 2:33well-known allotropes of carbon are
  44. 2:35morphis carbon graphite and Diamond
  45. 2:38which one of these allotropes can be
  46. 2:41used as anal in aluminium reduction
  47. 2:47process
  48. 2:49amorphous the amorphous form is
  49. 2:51essentially graphite but not held in a
  50. 2:53crystalline macro
  51. 2:56structure
  52. 2:57graphite at normal pressur carbon takes
  53. 3:00a form of graphite in which each atom is
  54. 3:03bonded
  55. 3:04trigonally two three others in a plane
  56. 3:06compos the fused hexagonal Rings the
  57. 3:10resulting network is two
  58. 3:11dimensional and the resulting flat
  59. 3:13sheets are stacked and loely bonded
  60. 3:15through weak van vse forces this gives
  61. 3:20graphite its softness and its cleaning
  62. 3:22properties the sheets slip easily past
  63. 3:24one another because of the
  64. 3:26delocalization of one of the outer
  65. 3:28electrons of each atom to form a fight
  66. 3:31Cloud graad fight conducts electricity
  67. 3:34but only in the plane of each calent
  68. 3:36bonded
  69. 3:38sheet
  70. 3:40Diamond that very high pressured carbon
  71. 3:43forms the more compact Petro Diamond
  72. 3:46here each atom is
  73. 3:48bonded tetrahedrally to four others thus
  74. 3:51making a three-dimensional network of
  75. 3:53puckered six membered rings of
  76. 3:55atoms that's why Diamond to be an
  77. 3:57excellent electrical insulator
  78. 4:03so it is obviously that alrod which is
  79. 4:05able to be used as anod material is
  80. 4:12graphite this is micro structure of
  81. 4:15graphite made asod due to the highest
  82. 4:18temperature might be possible happen in
  83. 4:20aluminium reduction pot still below 1,
  84. 4:24100° C so it is no need to prepare
  85. 4:27denser graphite just enough in between
  86. 4:301,000° c 1, 1400° c
  87. 4:35[Music]
  88. 5:07what criteria are needed from
  89. 5:09[Music]
  90. 5:11anod criteria for anodes one high
  91. 5:16resistance to gasification in order to
  92. 5:18minimize dusting and excess of carbon
  93. 5:20consumption two sufficient mechanical
  94. 5:23strength for structural integrity and
  95. 5:25handling three Clow specific electrical
  96. 5:28resistance value for power consumption
  97. 5:31four high Elemental Purity to avoid
  98. 5:34contaminating the reduced metal and
  99. 5:36excess anal consumption five high
  100. 5:39thermal shock resistance to avoid cell
  101. 5:45disruptions where is our positioned in
  102. 5:47these tough
  103. 5:50demand one
  104. 5:53gd80 typical
  105. 5:561.55
  106. 5:581.65 in Alum 1.64
  107. 6:031.69 status better two
  108. 6:08bd80 typical
  109. 6:111.50
  110. 6:131.60 in Alam
  111. 6:161.59
  112. 6:181.65 status better three AP typical 0.5
  113. 6:272.0 in Alam
  114. 6:300.3
  115. 6:320.5 status better for CS typical 40 55
  116. 6:41in Alum 28 49 status better five FS
  117. 6:50typical 8.0
  118. 6:5314.0 in Alam 11.0
  119. 6:5815.0 status better 6 TC typical 3.0
  120. 7:074.5 in Alum 3.2
  121. 7:114.0 status 7
  122. 7:16R2 typical 65 990 in Alum 89
  123. 7:2393 status better 8 r rc2
  124. 7:30typical 84
  125. 7:3295 in Alum 95
  126. 7:3797 status
  127. 7:47better great is it so difficult to
  128. 7:50achieve these
  129. 7:56figures unfortunately no at all
  130. 8:00no sacred matters
  131. 8:05here everything has been striped by R&D
  132. 8:14carbon we just follow it in the correct
  133. 8:16direction and
  134. 8:23doing some proper adjustments to adapt
  135. 8:26plant condition and current
  136. 8:31raw material is being used here the
  137. 8:34steps of anod
  138. 8:44manufacturer let's talk about the first
  139. 8:47step raw
  140. 8:50material
  141. 8:57CX caline Coke
  142. 9:00green Coke is residual fraction of
  143. 9:02petroleum or crude oil which has a very
  144. 9:04weak amorphous structure and still has
  145. 9:06volatile matter in between 8 up to 12%
  146. 9:09cook through delayed cooking process
  147. 9:11then calcinated by giving heat treatment
  148. 9:13to make it as electric quality Coke or
  149. 9:15caline
  150. 9:19Coke the Coke's texture
  151. 9:43smelter grade Cokes should have not too
  152. 9:45high real density and having tolerable
  153. 9:47impurities content to High real density
  154. 9:50will bring worse consequence during
  155. 9:52production and at last giving impact to
  156. 9:56Quality pitch
  157. 10:01for bonding grains it is used binder
  158. 10:04from liquefied
  159. 10:08CDP colar pitch col tar which is dewied
  160. 10:13heated up to approximately 350° Kel use
  161. 10:16and finally flash cold distillation
  162. 10:18process will become cold tar pit so what
  163. 10:22is cold tar pit complex mixture between
  164. 10:25polycyclic aromatic and heterocyclic
  165. 10:27compounds with aliphatic and function
  166. 10:29groups attached to the rinks
  167. 10:31approximately 90% of col tar pitch
  168. 10:34consists of three up to seven ring
  169. 10:35aromatic compounds with molecular
  170. 10:37weights ranging between 170 up to 380
  171. 10:41the remaining portion is made up of
  172. 10:43higher molecular weight carbonaceous
  173. 10:45materials that are not soluble why col
  174. 10:48tar pitch is choosed as binder one
  175. 10:51strong adherence or bonding to the
  176. 10:53aggregate two satisfactory wedding
  177. 10:57characteristics three High cooking value
  178. 11:00yielding a strong structure fourth low
  179. 11:03relative cost and ready avability in
  180. 11:05large quantities five low Ash and sulfur
  181. 11:09content six smooth volatile emission
  182. 11:12across the anode Bay temperature
  183. 11:22range cold tar pitch properties one
  184. 11:26softening point is used to describe the
  185. 11:28change in Pitch between a solid to
  186. 11:30liquid form two cooking value is an
  187. 11:34indicator of the likely residual carbon
  188. 11:35retained in the form of pitch Coke after
  189. 11:38baking three pitch density and CH ratio
  190. 11:42is an indication of the pitch
  191. 11:43aromaticity denser pitches have a higher
  192. 11:46aromaticity and thus produce denser
  193. 11:48baked anodes kesy of a binder carbon
  194. 11:50yield four quinine insoluble or Qi
  195. 11:54describes the amount of particles in
  196. 11:55soluble in quinine solvent alpha
  197. 11:57particles to be qi
  198. 11:59there are two type of Qi one primary
  199. 12:03formed in the coke oven so it is good
  200. 12:05for anode quality to secondary and
  201. 12:08mesophase formed by additional heat
  202. 12:09treatment note mesophase is harmful to
  203. 12:12anode quality five toine and solubles or
  204. 12:16TI beta resin is TI reduced by Qi it
  205. 12:20will give beneficial to bond your
  206. 12:22forming ability of pitch with Coke
  207. 12:24particles six viscosity is used to guide
  208. 12:28handling pitch liquid form and paste
  209. 12:29mixing and forming seven distillation of
  210. 12:33lighter fractions lower temperature
  211. 12:35distillation of the lighter fractions is
  212. 12:37a measure of the pitch volatile content
  213. 12:39and lighter fractions that are released
  214. 12:41in the temperature range 270° cus up to
  215. 12:45360°
  216. 12:46CSUS 8 ash content is an indicator of
  217. 12:50total impurities in
  218. 12:56Pitch the most important parameter from
  219. 12:59CDP is s
  220. 13:17p the material comes from rotting plant
  221. 13:21according to R&D carbon dust and Grains
  222. 13:24less than 1 mm must not be recycled and
  223. 13:26treated as waste
  224. 13:36how it could be what is the reason for
  225. 13:39R&D carbon the answer will come in a
  226. 13:46moment the last sodium content increases
  227. 13:49higher in line with thiner grains so
  228. 13:53that's why it is strictly not
  229. 13:54recommended in order to get better anal
  230. 13:57the bad character H can tent in ther
  231. 13:59should be minimized in usage for
  232. 14:03recycling that's all for the first step
  233. 14:06of anod manufacture next I'm going to
  234. 14:09explain how to make
  235. 14:20paste let's talking about the second
  236. 14:23step making good
  237. 14:26paste paste
  238. 14:31raw materials for paste are Aggregate
  239. 14:33and binder let's talk these raw
  240. 14:35materials one by one starting with
  241. 14:38aggregate aggregate is a mixing of Cokes
  242. 14:40and butts there are two preconditions
  243. 14:43should be fulfilled to get better
  244. 14:45aggregate one aggregate grains
  245. 14:47composition should be in the determined
  246. 14:53grometry according to rmd carbon there
  247. 14:56are four possibilities of grometry
  248. 14:59one intended to make denser green block
  249. 15:02with low porosity which is at last after
  250. 15:04baking it is H we can get high r value
  251. 15:07this kind of granulometry is our choice
  252. 15:10two intended to make denser green block
  253. 15:13with low porosity which is at last after
  254. 15:15baking it is hoped we can get low AP
  255. 15:17value unfortunately this kind of
  256. 15:20granulometry caused weaker physical
  257. 15:22strength three intended to make stronger
  258. 15:25anal after baking but unfortunately this
  259. 15:27kind of granulometry has lower R and A
  260. 15:30values fourth it must be avoided the
  261. 15:33worst grometry
  262. 15:38option our choice granulometry no one in
  263. 15:41implementation organized such
  264. 15:46as the granulometry or distribution of
  265. 15:49grain
  266. 15:50size to have denser anod the
  267. 15:54grometry should be arranged as the first
  268. 15:57course 16 mm down to 8 mm is
  269. 16:0110% the second course 8 mm down to 4 mm
  270. 16:05is
  271. 16:0610% medium to millime down to
  272. 16:090.125 mm is
  273. 16:1230% find below 0.125 mm is 50%
  274. 16:37two aggregate impurities side. e sodium
  275. 16:40calcium nickel and padium should be
  276. 16:42lower than determined values impurities
  277. 16:46should be attained in certain tolerable
  278. 16:51range catalytic
  279. 16:53impurities impurities which give bad
  280. 16:55impact to metal quality silicium Iron
  281. 16:58vadium nickel titanium and Lead
  282. 17:01impurities which give bad impact to
  283. 17:03anode consumption vadium nickel sodium
  284. 17:06potassium and calcium impurities which
  285. 17:09give bad impact to energy and current
  286. 17:11efficiency padium and
  287. 17:13phosphorus impurities which give bad
  288. 17:16impact to pollution sulfur hydrogen and
  289. 17:22Lead now I show how to prepare Cokes
  290. 17:33Co dis harded from silos by ratio high
  291. 17:35sulfur low sulfur equals 60 minutes and
  292. 17:3840
  293. 17:50seconds through damper DP if Coke Silo
  294. 17:53level is still above 40% no need bypass
  295. 18:09in server sr1 grains separated into the
  296. 18:12size batch above 18 mm and in range
  297. 18:16three 18 mm
  298. 18:30in silver sr2 grains separated into
  299. 18:33three size batch range three 1 mm range
  300. 18:371 0.2 mm and Below 0.2
  301. 18:53mm grains with size over 18 mm is
  302. 18:56crushed by Crusher to be ther than 5 mm
  303. 19:00and then send back to
  304. 19:13sr1 the Surplus in in one feedback into
  305. 19:16Crusher to increase finer grain size
  306. 19:19product
  307. 19:32to get finess grains with size below 0.2
  308. 19:35mm M into
  309. 19:48milk the Surplus inin to feedback to
  310. 19:51tube M to increase production of finess
  311. 20:07fine comes from dust collecting system
  312. 20:09or bag filters
  313. 20:35pay attention on the texture comparison
  314. 20:37between coses and butts
  315. 21:00let's magnify and after doing it can you
  316. 21:02catch any differences between them
  317. 21:31black color on coke is more dominant
  318. 21:33than butts these black color spots are
  319. 21:36assumed as
  320. 21:38porosity butts have denser texture than
  321. 21:41Cokes or in other words butts is weer
  322. 21:44than CES next images show which one is
  323. 21:47the best composition we should take
  324. 21:50composition one one all is buts two at
  325. 21:56the same volume it is weer than
  326. 21:58composition two and three three bonding
  327. 22:01among grains is not enough strong due to
  328. 22:03have only gluing and no
  329. 22:05anchoring for their reactivity and a
  330. 22:08permeability of the product anod will be
  331. 22:11worse so obviously that composition one
  332. 22:14is not
  333. 22:22recommended composition two one all is
  334. 22:26CX two at the same volume it is lighter
  335. 22:30than composition one and three three it
  336. 22:33is going to consume more binder four
  337. 22:37many problems will occur after
  338. 22:39baking so obviously that composition to
  339. 22:42is not also
  340. 22:49recommended composition three one mix
  341. 22:53between butts and cokes two at the same
  342. 22:57volume it has an ideal weight three
  343. 23:00optimal pitching can get obviously this
  344. 23:04is the composition should be applied
  345. 23:31point to be aimed is how to get the best
  346. 23:33composition between butts C in aggregate
  347. 24:17Based on data showing in the chart there
  348. 24:19are three conditions should be paid
  349. 24:21attention carefully one benefit got by
  350. 24:24using corer butts grain grain size in
  351. 24:27between 0 5 til to 16 mm is reducing
  352. 24:30porosity up to
  353. 24:3270% two meanwhile corser Co grain
  354. 24:36decreases 50% porosity three significant
  355. 24:40impact coming from finer grain either
  356. 24:42CES or butts let's say it's able to
  357. 24:45reduce porosity above
  358. 24:4790% in this range area it's better to
  359. 24:50utilize butts in order to increase
  360. 24:53weight and at last will be increased the
  361. 24:55density
  362. 25:10in this range area it's better to
  363. 25:12utilize butts in order to increase
  364. 25:14weight and at last will be increased the
  365. 25:16density
  366. 25:28in this range area consider to use same
  367. 25:30portion of Cokes and
  368. 25:42butts maximize Cokes in this area there
  369. 25:46are no significant white difference this
  370. 25:48can also avoid dirty butts thus entering
  371. 25:51the aggregate so let's skin the density
  372. 25:54of butts and cokes on each areas
  373. 26:06from the granulometry composition we
  374. 26:08have chosen we can get
  375. 26:20data now we make a simulation to look
  376. 26:22for the best composition to get higher
  377. 26:24density
  378. 26:49let's do trial and error method to fill
  379. 26:51the table
  380. 27:24but ratio equals 34% and vbd aggregate
  381. 27:27equals 0
  382. 27:299,323 g/
  383. 27:31CC CDP must be in liquid form in order
  384. 27:34to act as binder but before talking
  385. 27:36further please acknowledge information
  386. 27:39regarding
  387. 27:45CDP in depth with CDP one by using many
  388. 27:50different kind of solvent like alcohol
  389. 27:53toine and
  390. 27:54quinoline substances on Pitch can be
  391. 27:57grouped as alzin molecular weight is
  392. 28:00under 100 toine soluble molecular weight
  393. 28:04100 tilted
  394. 28:061,000 quinoline soluble molecular weight
  395. 28:091,000 till to
  396. 28:183,000 two the sticky characteristic of
  397. 28:22pitch conted mainly by Beta resin which
  398. 28:25is a difference of quinoline insoluble
  399. 28:27toine ins soluble beta resin equals KY T
  400. 28:32note more beta resin greater than better
  401. 28:34sticky characteristic of
  402. 28:36binder so to represent more beta Risin
  403. 28:39greater than increase amount of key this
  404. 28:42is commonly done by add lighter
  405. 28:44fractions into
  406. 28:46desolation this will increase the risk
  407. 28:48of metaphase appearance
  408. 29:07three sometimes too high key content
  409. 29:09will give bad impact to pump
  410. 29:12performance it's strainer clog by a thin
  411. 29:14layer so be wise in choosing CDP
  412. 29:29mesophase theoretical
  413. 29:31review when Pitch is made aeromatic
  414. 29:34systems are growing up in thermolyses
  415. 29:36and leads to a
  416. 29:37sufficiency High concentration of large
  417. 29:40aeromatic systems with molecular weights
  418. 29:42approximate to 600
  419. 29:44a.m mesophase occurs if some critical
  420. 29:47parameters EG viscosity heating rate and
  421. 29:50others are met the mesophase is strongly
  422. 29:53an isotropic and takes a spherical form
  423. 29:55in order to minimize its surface energy
  424. 30:03further about
  425. 30:04mapase at further heating or increasing
  426. 30:07residance time more and more mesophase
  427. 30:09is formed from the isotropic pitch the
  428. 30:12size of the mesophase Spheres increases
  429. 30:14and they start to coales into bigger and
  430. 30:17bigger anisotropic
  431. 30:19areas the transition from a flowing or
  432. 30:21plastic pitch to a rigid SM Coke green
  433. 30:23Coke occurs in a narrow temperature
  434. 30:26interval around 500 ° C still the
  435. 30:29significant amount of hydrogen is
  436. 30:31present but most will be gone when the
  437. 30:33temperature reaches 800° C so obviously
  438. 30:38that too much mesap phase with high
  439. 30:40diameter will leave behind voids after
  440. 30:42baking process it's clearly harming anod
  441. 30:45quality and this is so
  442. 30:51bad this data informed the amount of
  443. 30:53mesophase and heat adjustment to keep
  444. 30:56hitch viscosity in order to keep as good
  445. 30:58binder
  446. 31:02agents this data informed the additional
  447. 31:04percentage of pitch in order to cover
  448. 31:06the existence of mesophase in
  449. 31:24binder what kind of pitching shall it be
  450. 31:26achieved in order to get good hod let's
  451. 31:29no kind of level pitch given into paste
  452. 31:32case
  453. 31:35one under
  454. 31:40pitching under pitching symptoms one dry
  455. 31:44paste two cracks on GB three underling
  456. 31:50lack of volatiles fourth poor mechanical
  457. 31:54properties five air burn problem in pot
  458. 31:58case
  459. 32:01two over
  460. 32:07pitching watch out over pitching at last
  461. 32:11and bond grains due to co greater than
  462. 32:13adhesion over ping
  463. 32:16symtoms one wet paste two glowing paste
  464. 32:22three extreme shrinkage four stum hole
  465. 32:26deformation SL slide ping five crack
  466. 32:30during baking excessive de
  467. 32:32validation six sticking of packing
  468. 32:36material seven high air permeability
  469. 32:39compressive strength and Young's
  470. 32:43modulus so what does the optimal
  471. 32:46pitching look like case
  472. 32:51three optimal
  473. 32:55pitching optimal pitching one still left
  474. 33:00void two no separate bonding among
  475. 33:03grains now we have came to how to
  476. 33:06achieve optimal hit thinging by setting
  477. 33:08correct binder
  478. 33:10ratio to do this firstly we have to know
  479. 33:14the limit of over pitching by comparing
  480. 33:16slumping on BB
  481. 33:38watch out look at figures 15% and next
  482. 33:42higher level in this range gb80 is not
  483. 33:46in line with bb80 anymore what does it
  484. 33:50mean yes of course gb8 can be made
  485. 33:54Higher by increasing binder level but
  486. 33:57result after baking delimitate it so
  487. 34:01this phenomenon becoming the first sign
  488. 34:05of over
  489. 34:07pitching secondly check the sticking
  490. 34:09either amount or pattern on
  491. 34:13BB remember there are two kind of sticky
  492. 34:17things on BB just after discharging from
  493. 34:20baking furnace one isolation CX two
  494. 34:26another blocks
  495. 34:28whatever the sticking kind this pointing
  496. 34:31to the second indicator of over pitching
  497. 34:34note we apply constrainted value
  498. 34:372% of sticking on BB from the total BB
  499. 34:44discharged listing the figures into Data
  500. 34:46Bonk for the next product please keeping
  501. 34:49this data Bonk
  502. 34:51update are there any different
  503. 34:53methods there are two methods to detect
  504. 34:56binder sufficiency
  505. 34:58it should be done by operator during
  506. 35:00inspection one physical inspection on GB
  507. 35:04condition looking for symptoms of over
  508. 35:07pitching like glowing on GB crust length
  509. 35:11shrinkage greater than 3
  510. 35:13mm two observation on paste condition
  511. 35:17just before forming like flexity tough
  512. 35:21for fragile now we have come into the
  513. 35:24making of
  514. 35:26paste
  515. 35:56e e
  516. 36:31beware kept the temperature of this
  517. 36:33pasted product all plus 10° see than
  518. 36:36temperature needed in forming machine
  519. 36:38what should be paid attention in
  520. 36:40knitting or mixing
  521. 36:43operation what should be paid attention
  522. 36:45inting or mixing
  523. 36:47operation one softening point is P value
  524. 36:50of the current
  525. 36:53CDT important an Alum using balling
  526. 36:57methods
  527. 36:58so it has to be adjusted by -5° C for
  528. 37:02operation purpose correlation between
  529. 37:06softening point and mixing temperature
  530. 37:08is described by equation Y = 1.48 X +
  531. 37:145.6 where y equals mixing temperature x
  532. 37:18equals softening point for
  533. 37:20example if SB equals 113° c so mixing
  534. 37:25temperature equals 172 8°
  535. 37:29C by implementing Black's principle we
  536. 37:32have formula for thermal
  537. 37:36balance let's say we have data s p of
  538. 37:40CDP from India equals 113° c binder
  539. 37:44ratio equals
  540. 37:4714.5% heating up temperature for CDP
  541. 37:50equals 210 de C heating up temperature
  542. 37:54for aggregate equals 160° c
  543. 37:57how big additional temperature should be
  544. 38:00given answer first we are looking for
  545. 38:03mixing
  546. 38:04temperature put in SB value into the
  547. 38:07first Formula we have
  548. 38:09172.2 4° C put in data into the second
  549. 38:13formula we have equation
  550. 38:160.145 asterisk 210 T =
  551. 38:200.855 asterisk T 160 so we will get t
  552. 38:26equal 16 7.25 de C greater than we need
  553. 38:305.59 de C more let's try to implement
  554. 38:34this
  555. 38:37formula please follow the movement of
  556. 38:39star pointer on the
  557. 38:55chart this situation takes place if no
  558. 38:58additional heat so it is strictly
  559. 39:07prohibited in order to achieve
  560. 39:09appropriate mixing
  561. 39:11temperature an additional heat from
  562. 39:13meter should be
  563. 39:24given two the second important fact
  564. 39:27during kneading process is specific
  565. 39:29mixing
  566. 39:31energy mixing energy the best practice
  567. 39:35in in Alam to get homogeneous taste is
  568. 39:38by
  569. 39:39implementing mixing energy inside a
  570. 39:41tight space from 8.9 up to 9.1 kilow
  571. 39:46flash T paste below this range paste
  572. 39:49looks dry Above This range paste looks
  573. 39:54wet three mixing time
  574. 40:09look either shorten or prolong the
  575. 40:11mixing time in fact it is no
  576. 40:18use important stuff related to mixing
  577. 40:21time too short makes under pitching too
  578. 40:24long may destroy granulometry of the
  579. 40:26grains
  580. 40:28what we want is sufficient time in order
  581. 40:30to give binder and finess centering
  582. 40:34macroporosity of grains to create anchor
  583. 40:36bonding among binder Matrix outside and
  584. 40:40inside
  585. 40:41grains note it is applied mixing time
  586. 40:44around 5 minutes please look at
  587. 40:47description comes in a moment inside
  588. 40:50meter forces C binder Matrix to enter
  589. 40:53Cox grains
  590. 41:00after cooling this binder Matrix will
  591. 41:02build stronger bonding compared to
  592. 41:03gluing only
  593. 41:30let's talk about the two Road step paste
  594. 41:36forming steps of shaking machine
  595. 41:41operation One charging paste into the
  596. 41:44ready mold note paste is not something
  597. 41:49liquid so it cannot fulfill the whole
  598. 41:52Space inside the mold automatically we
  599. 41:55have to arrange hits spreading evenly
  600. 41:58during filling time in order to avoid
  601. 42:01sticking of paste in the mold wall
  602. 42:04precaution actions should be done before
  603. 42:06forming like a heating up or keeping
  604. 42:09temperature stable B spraying special
  605. 42:12oil and water in the wall
  606. 42:14regularly see removing resident the mold
  607. 42:17from the previous
  608. 42:24forming in order to get one side having
  609. 42:27better density we can increase thickness
  610. 42:30on this side paste profile intentionally
  611. 42:33created not
  612. 42:35flat or you can't try for the opposite
  613. 42:39side two put cover weight down and then
  614. 42:43lock up what should be paid attention
  615. 42:46regarding cover weight a to waight the
  616. 42:49cover weight leads to grain
  617. 42:50destruction and thus to an insufficient
  618. 42:53strength of the EG node B to light the
  619. 42:56cover weight result in a poor density
  620. 42:59and an excessive gas
  621. 43:03permeability note specific forming
  622. 43:06pressure versus anal
  623. 43:08crosssection vation y = -
  624. 43:124591 x superscript 3 + 1655 x
  625. 43:16superscript 2 1931 x +
  626. 43:208.7 y equals specific forming pressure
  627. 43:23bar x equal anod crosssection m
  628. 43:26superscript 2
  629. 43:28two three evacuating unnecessary gas
  630. 43:32repa emission by vacuum usually for
  631. 43:35better result man make it below 120
  632. 43:42MPR it's time for vibrating now
  633. 44:05fourth vibro compassion operation
  634. 44:08tips paste temperature put into the mold
  635. 44:11should be in between
  636. 44:12155° C til to 165° C avoid paast
  637. 44:18temperature variance Federal into mold
  638. 44:19vary more than plus SL 2° C in order to
  639. 44:24get better result it is strongly
  640. 44:26suggested to make put paste temperature
  641. 44:29close to the highest constraint equals
  642. 44:32165° c this effort is going to decrease
  643. 44:36viscosity so it is easier for grains
  644. 44:39moving to find its Optimum place in mold
  645. 44:42during
  646. 44:49vibration DB and are o this is control
  647. 44:54program on the vro comping machine
  648. 44:57control principle by this program can be
  649. 44:59explained one the first priority the
  650. 45:03machine look for gb80 value or GB height
  651. 45:07if one of these Target is found then
  652. 45:10stop two secondly if during set maximum
  653. 45:14fpr compassion running these two Targets
  654. 45:17don't get then
  655. 45:18stop note the machine is completed by
  656. 45:21weighing scale and height sensor so it
  657. 45:25is able to adjust the amount of
  658. 45:27paste Federal if the height of previous
  659. 45:29block down
  660. 45:36below
  661. 45:38beware just after forming block exhibit
  662. 45:41a low mechanical stability due to the
  663. 45:43softness of binder pitch in order not to
  664. 45:47damage the block handling with care is a
  665. 45:50must so to release block from mold
  666. 45:53Pusher should be run gently it finish
  667. 45:57prepare to form next block
  668. 46:29cooling after forming after forming GB
  669. 46:32temperature is still high it exhibits
  670. 46:35low mechanical stability due to this
  671. 46:38reason it needs to be
  672. 46:40cooled this is very important phase on
  673. 46:42the making of anodes mishandling will
  674. 46:45cause damage on GB one cool to intensify
  675. 46:49may
  676. 46:50cause surface fissures are generated due
  677. 46:53to shrinkage of GB crust two
  678. 46:56insufficient cooling may
  679. 46:58cause damage on GB during subsequent
  680. 47:01handling storage and
  681. 47:03processing here in a moment show to you
  682. 47:06the steps of cooling
  683. 47:16phase be careful this period needs a lot
  684. 47:19of care or just leave it more safe
  685. 47:32this is a sample when weak crust is in
  686. 47:34dangerous period but handled
  687. 48:06just before I end this
  688. 48:08presentation let me explain how to keep
  689. 48:11the
  690. 48:23quality first of all you should know
  691. 48:26well the basic te knowledge NGB
  692. 48:28production do you know
  693. 48:37it the most important thing from paste
  694. 48:40plant to make sure the GB product always
  695. 48:43in the good quality or just to control
  696. 48:46impurities content coming from raw
  697. 48:48material and get ideal
  698. 48:50gb80 as simple as that isn't it
  699. 48:58I have developed the formula to predict
  700. 48:59ano quality based on GD data calculation
  701. 49:03result with this Formula compared by
  702. 49:05actual result show just the little
  703. 49:08difference plus minus
  704. 49:141% 1 R2 equal -
  705. 49:18216218 then I
  706. 49:2197215 3 v 105.4 one5 no plus 190 . 783
  707. 49:27CA + 1.6 for 2 s 2.33 6 gb8 + 106.1
  708. 49:34183 where R2 equals air reactivity
  709. 49:37residue percent then I equals nickel
  710. 49:39content percent V equals padium content
  711. 49:42percent a equals sodium content percent
  712. 49:45C equals calcium content percent s
  713. 49:48equals sulfur content
  714. 49:53percent two r r c o 2 = -
  715. 49:58238.9 for1 c 24.25 3 46.0 to2 V plus
  716. 50:051.15 s + 9652
  717. 50:084 where R rc2 equals Co to reactivity
  718. 50:13residue percent C equals calcium content
  719. 50:15percent equals sodium content percent V
  720. 50:19equals padium content percent s equals
  721. 50:21sulfur content percent
  722. 50:28so by controlling each impurities
  723. 50:30involved and arrange ideal gb80 best
  724. 50:32quality anodes are in our
  725. 50:35hand regarding achievement and ideal gb8
  726. 50:38like or dislike it depends on the
  727. 50:40goodness of equipment and skill and
  728. 50:43blending raw material experience is the
  729. 50:46key but here I just share some tricks
  730. 51:03there are two conditions Down Under and
  731. 51:05Over the Top basically both of them are
  732. 51:09caused by
  733. 51:10grometry counter measure for down under
  734. 51:13one increase the usage of corser butts
  735. 51:16material if enabled two in case you
  736. 51:20don't have corser butts consider
  737. 51:22increased butts
  738. 51:23ratio three in case you have only
  739. 51:26sufficient butt stock consider to
  740. 51:28decrease production capacity counter
  741. 51:31measure for over the top one decrease
  742. 51:35the usage of corser butts material if
  743. 51:37enabled two in case you don't have finer
  744. 51:41butts consider to crush it three in case
  745. 51:45you have too much butt stock consider to
  746. 51:47increase production
  747. 51:54capacity in this position the cause is
  748. 51:57still same with down
  749. 51:59undercase just use the same trick to
  750. 52:01overcome this
  751. 52:08problem in this position the cause is
  752. 52:11informing machine or Neer just follow
  753. 52:14the tricks already explained to overcome
  754. 52:16this
  755. 52:25problem for

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