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The Donut Lab Solid-State Battery Situation is Crazy — Transcript

by Ziroth · 2,192 words · 345 segments · language en · Watch on YouTube

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  1. 0:00In case you haven't heard, a company
  2. 0:02called Donut Lab claimed to have solved
  3. 0:04a trillion dollar problem with their
  4. 0:06miracle battery. It promises to charge
  5. 0:09fast, store huge amounts of energy,
  6. 0:12require no critical materials, and last
  7. 0:15literal generations, all whilst being
  8. 0:18cheaper than anything on the market. If
  9. 0:21you think that sounds too good to be
  10. 0:22true, then you're not alone. And over
  11. 0:25the last 10 months since the
  12. 0:27announcement, Donut Lab haven't done
  13. 0:29much to settle the debates. In fact, my
  14. 0:32last video on Donut Lab outlined how
  15. 0:35data from their previous test reports
  16. 0:37match commercially available lithium ion
  17. 0:40cells. And now, in a strange twist of
  18. 0:44events, they've started testing a
  19. 0:46completely different set of battery
  20. 0:48cells, and they can't even prove that
  21. 0:50those are rechargeable. So, let's see
  22. 0:53how Donut Lab responded to my last
  23. 0:55video, the outcome of some recent legal
  24. 0:58proceedings, and why their new test data
  25. 1:01is even more questionable than before.
  26. 1:04I'm Ryan MᶜNellis, and this is a Zero to
  27. 1:06Deep Dive.
  28. 1:10Let's start by quickly going over Donut
  29. 1:12Lab's response to my last video, because
  30. 1:14they made some really good technical
  31. 1:16counterpoints to my claims.
  32. 1:19Oh, wait. No, they didn't. They instead
  33. 1:21went after me as an individual and
  34. 1:23didn't address a single one of my
  35. 1:25points. Like the voltage curve matching
  36. 1:28that of a lithium ion cell, or the cell
  37. 1:30expanding in the same way a lithium ion
  38. 1:33cell with a graphite anode would expand.
  39. 1:36Publicly, they've said that I'm ignoring
  40. 1:38the facts, but my points were based on
  41. 1:41their own test data and peer-reviewed
  42. 1:43publications. I will say that a
  43. 1:46highlight for me in Donut Lab's response
  44. 1:48was this meme posted by a friend of
  45. 1:50their CEO, which is truly terrifying.
  46. 1:53So, instead of addressing any of my
  47. 1:55concerns, Donut Lab have just said that
  48. 1:58my criticism comes from having worked
  49. 2:00with their competitors, including CATL,
  50. 2:04BYD, Panasonic, and BMW. I have worked
  51. 2:07with these companies and will hopefully
  52. 2:09work with them again because they give
  53. 2:11me real test data, show me real
  54. 2:13demonstrations, and have patents that
  55. 2:16back up their products that they even
  56. 2:18ship with warranties.
  57. 2:20>> [music]
  58. 2:20>> And either way, none of that changes
  59. 2:22anything about the points I made in my
  60. 2:24previous video. None of those points
  61. 2:27depend on who I've worked with, and
  62. 2:29anyone can check the data for
  63. 2:31themselves. One thing that does concern
  64. 2:34me, though, is what I see as an attempt
  65. 2:36by Donut Lab to silence its critics
  66. 2:38through the court system via a lawsuit
  67. 2:41brought about by its subsidiary Nordic
  68. 2:43Nano.
  69. 2:45Nordic Nano Group, which is now owned by
  70. 2:47Donut Lab, has just lost much of a legal
  71. 2:50battle against Lauri Peltola, who is one
  72. 2:53of the co-founders. I've got the court
  73. 2:55documents here directly from the court,
  74. 2:57though I can't share them publicly. It
  75. 2:59turns out that after Lauri started
  76. 3:01talking to the press, Nordic Nano Group
  77. 3:03went to the Helsinki District Court
  78. 3:05asking for an order to stop him from
  79. 3:08publishing any of their confidential
  80. 3:09information or the information of their
  81. 3:12partners and suppliers backed with fines
  82. 3:15of up to 100,000 euros. The court
  83. 3:17actually granted an emergency but
  84. 3:20temporary gagging order in May to stop
  85. 3:22Lauri from talking to the press.
  86. 3:24However, after hearing his side of the
  87. 3:26story, they lifted that order and
  88. 3:28refused the rest of Nordic Nano Group's
  89. 3:30demands to stop Lauri talking to the
  90. 3:32press, finding them too vague to
  91. 3:34enforce. Nordic Nano Group did win back
  92. 3:37Lauri's work laptop and phone, and the
  93. 3:39court rejected Lauri's claims that the
  94. 3:42case was an abusive lawsuit.
  95. 3:44>> [music]
  96. 3:44>> Interestingly, though, Nordic Nano Group
  97. 3:46wanted the whole case itself to be kept
  98. 3:49secret. It initially asked for the
  99. 3:51entire application, including the
  100. 3:54request to stop Laurie publishing any
  101. 3:56more, to be sealed for 25 years.
  102. 3:59That raises a question.
  103. 4:02If Donut Lab says Laurie was never in on
  104. 4:05its battery team and has no up-to-date
  105. 4:07knowledge of the technology, then
  106. 4:09[music] why did its own subsidiary go to
  107. 4:12court to stop him speaking publicly? If
  108. 4:15their public message is true, in which
  109. 4:17they say that Laurie knows nothing, then
  110. 4:20the aim of the court case couldn't be to
  111. 4:23protect genuine secrets, because he
  112. 4:25wouldn't have had any. It seems to me
  113. 4:28more about keeping the fraud allegations
  114. 4:30quiet, especially because they wanted
  115. 4:32the whole trial to be kept secret, too.
  116. 4:35I will say there are still ongoing court
  117. 4:37proceedings relating to this, but it
  118. 4:39doesn't look good for Donut Lab and the
  119. 4:42team. Okay, so that's the legal stuff
  120. 4:44out of the way, and now let's move on to
  121. 4:46the new data published by Donut Lab. And
  122. 4:49honestly, I've lost count of all the
  123. 4:51different cells Donut Lab have now
  124. 4:53tested. So, let's look at that after a
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  151. 6:02link in the description or the on-screen
  152. 6:04QR code. Now, let's look at the other
  153. 6:07new cells Donut Lab are testing and
  154. 6:09apologies if you're losing track of all
  155. 6:11of them, I am too.
  156. 6:13Firstly, there was the one that fast
  157. 6:15charged and then got damaged after being
  158. 6:17exposed to high temperatures, puffing
  159. 6:19and losing over a half its usable
  160. 6:21capacity. They've since introduced
  161. 6:23another cell which is apparently version
  162. 6:261.5.
  163. 6:27Donut Lab have now admitted that the
  164. 6:29first version couldn't actually reach
  165. 6:32their claimed 400 watt hours per
  166. 6:33kilogram energy density, but this new
  167. 6:36version has been verified at 409 watt
  168. 6:40hours per kilogram with no other tests
  169. 6:42performed. This energy density is in
  170. 6:45line with commercially available high
  171. 6:47energy lithium ion cells. They also
  172. 6:49claim that there's a new new version
  173. 6:52being released soon which I think is
  174. 6:53version two and that will also hit some
  175. 6:56of their other claims like fast
  176. 6:58charging. This strongly suggests the
  177. 7:01cell tested at 409 watt hours per
  178. 7:03kilogram is not able to fast charge, but
  179. 7:06the new new one will be able to. This is
  180. 7:09convenient timing when other companies
  181. 7:11like Amprius and BEI have recently
  182. 7:14released high energy density cells that
  183. 7:16can also fast charge, both based on
  184. 7:19lithium ion chemistries. However, for
  185. 7:21me, the strangest part relates to a new
  186. 7:24set of cells that Donut Lab have started
  187. 7:27testing. And yes, there are now more
  188. 7:29cells which are completely different in
  189. 7:32both function and design to the other
  190. 7:35ones they've tested.
  191. 7:36The claim is that these new cells use a
  192. 7:39bipolar stack design and from
  193. 7:42third-party test data, it's clear that
  194. 7:45there are indeed stacks of anode and
  195. 7:47cathode layers, and the cell produces a
  196. 7:50voltage. But, there's more to this than
  197. 7:52meets the eye. The idea of bipolar cells
  198. 7:55is actually a well-researched field. In
  199. 7:58a bipolar cell, a shared conductive
  200. 8:01plate has anode material on one face and
  201. 8:05cathode material on the other. If you
  202. 8:07stack these plates together, the voltage
  203. 8:10adds up in series, all neatly inside one
  204. 8:13sealed cell. This means you can save
  205. 8:16space compared to having lots of
  206. 8:19individual cells stacked together.
  207. 8:21Despite the possible advantages, the
  208. 8:23cells have some challenges, and a lot of
  209. 8:25them relate to lifespan. Meaning, the
  210. 8:28cell won't be able to charge or
  211. 8:30discharge many times before it becomes
  212. 8:33unusable. But, Donut Lab have done one
  213. 8:36better than this.
  214. 8:37Their cells don't appear to be able to
  215. 8:40charge or discharge at all. Yes, you
  216. 8:44understood that right. It appears the
  217. 8:46new cells from Donut Lab aren't even
  218. 8:49rechargeable batteries. The test report
  219. 8:52from Intertek said this, "Intertek have
  220. 8:55not verified that the device under test
  221. 8:58is a functioning battery cell which can
  222. 9:00be electrically discharged and charged."
  223. 9:03The Donut Lab CEO also actively refused
  224. 9:07to comment on if the cells could be
  225. 9:09recharged, and the company never gave me
  226. 9:11a response.
  227. 9:12I did track down another company
  228. 9:14involved called Future Motive by seeing
  229. 9:17who commissioned the latest Donut Lab
  230. 9:18reports. And when I phoned them up, they
  231. 9:21were also unable to confirm whether the
  232. 9:23latest cells were rechargeable. The
  233. 9:26reason it's important that the cell
  234. 9:28doesn't appear rechargeable is because
  235. 9:30non-rechargeable bipolar cells are
  236. 9:33nothing new. In fact, the earliest
  237. 9:36battery, Volta's pile from around 1800,
  238. 9:40was a bipolar stack. I've literally got
  239. 9:43a bipolar stack here. It's got layers of
  240. 9:46copper and zinc, and then felt in
  241. 9:48between it, and if you add an
  242. 9:49electrolyte like salt water, it will
  243. 9:52conduct and work as a bipolar stack.
  244. 9:55Each pair gives around 0.8 volts, so if
  245. 9:58I was to stack five of them together,
  246. 10:00I'd get about 4 volts.
  247. 10:02Um so, I think maybe I have a
  248. 10:04billion-dollar battery company. Like
  249. 10:06with all electrochemical systems, the
  250. 10:09voltage of my bipolar cells are
  251. 10:11determined by the materials. If you
  252. 10:13change the materials, you change the
  253. 10:15voltage.
  254. 10:17Which is how we know that the latest
  255. 10:19bipolar cell from Donut Lab uses
  256. 10:21different materials to the high-energy
  257. 10:23density or fast-charging ones they've
  258. 10:25tested before. The voltages we've seen
  259. 10:28are 12.3 volts, 7.8 volts, 5 volts, and
  260. 10:333.3 volts. If these are stacks of layers
  261. 10:36in series, then we can assume they are
  262. 10:39eight, five, three, and two layers,
  263. 10:41which give 1.54 volts, 1.56 volts, 1.67
  264. 10:47volts, and 1.65 volts per layer for each
  265. 10:51of these battery cells. I picked these
  266. 10:53number of layers as they are the whole
  267. 10:55numbers that give a consistent result,
  268. 10:58so do treat this as a hypothesis.
  269. 11:00But that voltage range we're seeing of
  270. 11:031.5 to 1.65
  271. 11:06volts per layer is typical of a
  272. 11:08zinc-based chemistry, like a cell using
  273. 11:11zinc and manganese dioxide.
  274. 11:14One using lithium in each layer would
  275. 11:16sit much higher, probably around 3 volts
  276. 11:19or more.
  277. 11:20This graph shows the electrode
  278. 11:22potentials for different material
  279. 11:24combinations, where the difference in
  280. 11:26voltage between the anode and cathode
  281. 11:28material dictates the cell voltage. You
  282. 11:31could pair different materials with
  283. 11:33lithium to get lower voltages. But, as
  284. 11:36the bipolar cell was shown to have no
  285. 11:37lithium, and its voltage matches with a
  286. 11:41zinc-based cell, that would be my best
  287. 11:43guess. This is funny to me because
  288. 11:46you're probably more familiar than you
  289. 11:48think with non-rechargeable
  290. 11:50zinc-manganese-based cells. As they are
  291. 11:53the conventional AA batteries that you
  292. 11:56can find in your TV remote. Guess I'm
  293. 11:58sat on another billion-dollar idea.
  294. 12:01It's not impossible that the cell
  295. 12:03they're testing is, in fact,
  296. 12:05rechargeable. They do exist. But, it's a
  297. 12:09wildly different cell to the others they
  298. 12:11have tested. This brings up the
  299. 12:13question, if you have a cell that you
  300. 12:16say doesn't contain any lithium, why
  301. 12:18would you test a different cell for its
  302. 12:21lithium content? This also makes the
  303. 12:24nail penetration and chemical analysis
  304. 12:26test that Donut Lab performed pretty
  305. 12:29useless, as they didn't do it on the
  306. 12:31high-energy-density cell that they
  307. 12:33tested, but instead the small,
  308. 12:36non-rechargeable bipolar prototype.
  309. 12:38Donut Lab didn't need to do a chemical
  310. 12:41analysis on this prototype cell to show
  311. 12:43it had no lithium or sodium. The
  312. 12:45voltages already suggested that.
  313. 12:48Though, I would be far more interested
  314. 12:50if it didn't contain any zinc. As a side
  315. 12:52note, non-rechargeable zinc-based
  316. 12:54batteries are actually really cool. You
  317. 12:57can even buy commercial zinc-air
  318. 13:00batteries that reach around 400 to 500
  319. 13:03watt-hours per kilogram, and they're
  320. 13:05commonly used in hearing aids, though
  321. 13:07they are single use. I feel like a
  322. 13:09broken record, but the same questions
  323. 13:12remain 10 months after the original
  324. 13:15announcement. Where is the cell that can
  325. 13:18fast charge, hold 400 watt-hours per
  326. 13:20kilogram, and last 100,000 cycles, all
  327. 13:24without lithium? Instead of running the
  328. 13:26tests that critics have asked for, they
  329. 13:29keep pulling new cells out of nowhere
  330. 13:31and testing those instead.
  331. 13:33I'm pretty confident that this will be
  332. 13:35the last video that I make on Donut app,
  333. 13:37but people wanted to know what had
  334. 13:39happened since I made my last video, so
  335. 13:41there it is.
  336. 13:43They've been testing a range of
  337. 13:44different cells, losing lawsuits, and
  338. 13:47making memes.
  339. 13:48So, if you've enjoyed this video, please
  340. 13:50consider subscribing. It's free and
  341. 13:52helps the channel a lot. You might also
  342. 13:54like some of our other videos, like this
  343. 13:56one on Tesla's new electric motor.
  344. 13:59And as always,
  345. 14:01thanks for watching.

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